Joining ZTA ceramic by using Dy2O3-Al2O3-SiO2 glass ceramic filler

In this paper, a novel Dy₂O₃-Al₂O₃-SiO₂ (DAS) glass ceramic was designed and prepared for joining zirconia toughened alumina (ZTA) ceramic. The crystallization, thermal expansion behavior and wetting behavior of the DAS glass filler were studied. The effect of cooling rate and joining temperature on the microstructure and flexural strength of joints was investigated. The results show that slow cooling rate (15 °C/min) leads to crystallization of brazing seam, which causes the formation of pores in the joints due to the large density difference between the glass and the crystalline phases. The dissolution of ZrO₂ from ZTA substrate into the filler during joining process improves the mismatch of the coefficient of thermal expansion (CTE) between the brazing seam and substrate. The maximum flexural strength of 535 MPa is obtained when the joining temperature and cooling rate are 1475 °C and 50 °C/min, respectively.     

Microstructure evolution and cooperative reinforcement mechanisms of Al2O3/Al2O3 joints brazed by low-melting borosilicate glass

The Al₂O₃/SiO₂–B₂O₃–Al₂O₃–Na₂O glass/Al₂O₃ joints reinforced cooperatively by glass matrix and in-situ Al₄B₂O₉ whiskers were obtained via a low-melting borosilicate glass braze. The composition of glass seam transformed from SiO₂–B₂O₃–Na₂O to SiO₂–B₂O₃–Al₂O₃–Na₂O due to continuous diffusion and dissolution of Al₂O₃. An appropriate amount of [AlO₄] units introduced into the glass braze played a vital role in strengthening the glass network structure resulting to considerably improved mechanical strength of the glass seam. Meanwhile, plenty of in-situ Al₄B₂O₉ whiskers growing from the Al₂O₃/glass braze interface to the center of glass seam in various directions generated. Three-dimensional crisscross structures were fabricated at the Al₂O₃/glass braze interface domains, where were enhanced by crack-bridging and pull-out effect of the whiskers. Generally, ascribed to the cooperative reinforcement of the glass matrix in the seam and in-situ Al₄B₂O₉ whiskers at Al₂O₃/glass braze interface domains through reactions of Al₂O₃ and borosilicate glass braze, strength of the as-brazed joints was promoted prominently. The shear strength of the joints reached a maximum of 61 MPa brazed at 1050 °C for 60 min.     

Noble-metal-free Co@Co2P/N-doped carbon nanotube polyhedron as an efficient catalyst for hydrogen generation from ammonia borane

Developing an efficient catalyst for hydrogen (H₂) generation from hydrolysis of ammonia borane (AB) to significantly improve the activity for the hydrogen generation from AB is important for its practical application. Herein, we report a novel hybrid nanostructure composed of uniformly dispersed Co@Co₂P core-shell nanoparticles (NPs) embedded in N-doped carbon nanotube polyhedron (Co@Co₂P/N–CNP) through a carbonization-phosphidation strategy derived from ZIF-67. Benefiting from the electronic effect of P doping, high dispersibility and strong interfacial interaction between Co@Co₂P and N-CNTs, the Co@Co₂P/N–CNP catalyst exhibits excellent catalytic performance towards the hydrolysis of AB for hydrogen generation, affording a high TOF value of 18.4 mol H₂ mol metal^?1 min^?1 at the first cycle. This work provides a promising lead for the design of efficient heterogeneous catalysts towards convenient H₂ generation from hydrogen-rich substrates in the close future.     

超声作用对镁合金表面电沉积层组织与性能的影响

通过设计中间过渡层,缩小AZ91D镁合金与沉积层镍之间的电位差,并以碱性锡酸盐镀液代替对人体和环境均有害的氰化物镀液,配合超声波作用,在AZ91D镁合金表面获得了电沉积镍层.利用SEM观察沉积层表面微观形貌,XRD、XPS对各处理层进行相组成检测.分析了锡酸盐镀液代替氰化物镀液对沉积层质量的影响,超声波对各沉积层沉积过程的影响以及对沉积层组织的细化作用.结果表明:碱性锡酸盐的使用提高了镀液的pH值,与酸性镀液相比较,减缓了镁合金在镀液中的腐蚀速率,为电沉积镍层在其表面的获得奠定了良好基础;各沉积层获得过程中,超声波的使用明显细化了各沉积层的组织,提高了其致密性,镀层的择优取向和耐腐蚀性能也得到改善.     

细晶TiAl基合金的制备及高温氧化行为

采用机械合金化及放电等离子烧结方法制备超细晶/纳米晶TiAl基合金,并利用差热分析仪进行循环高温氧化试验,研究粉末机械合金化对烧结细晶粒TiAl基合金组织及高温氧化性能的影响。结果表明,球磨是获得细晶粒组织的原因,粉末经球磨及放电等离子烧结后,形成了细小、球状的TiAl和Ti3Al相组织;该细晶粒组织在高温循环氧化条件下显示出较高的抗氧化性,且随Nb量增加抗氧化性得到提高,升温阶段的氧化速率最快。     

Fluorene derivatives for highly efficient non-doped single-layer blue organic light-emitting diodes

Diphenylamino- and triazole-endcapped fluorene derivatives which show a wide energy band gap, a high fluorescence quantum yield and high stability have been synthesized and characterized. Single-layer electroluminescent devices of these fluorene derivatives exhibited efficient deep blue to greenish blue emission at low driving voltage. The single-layer OLED of PhN-OF(1)-TAZ shows a maximum current efficiency of 1.54 cd/A at 20 mA cm⁻² with external quantum efficiency (EQE) of 2.0% and CIE coordinates of (0.153, 0.088) in deep blue region, while the single-layer device of oligothienylfluorene PhN-OFOT-TAZ shows a maximum brightness of 7524 cd/m² and a maximum current efficiency of 2.9 cd/A with CIE coordinates of (0.20, 0.40) in greenish blue.     

搅拌摩擦加工制备Al6061/SiC复合材料的耐蚀性研究

目的 利用搅拌摩擦加工技术制备纳米SiC铝基复合材料,研究经过纳米粒子的添加和FSP作用后,其耐腐蚀性能的变化及原因.方法 室温条件下,在3.5％NaCl溶液中,通过电化学阻抗谱和动电位极化曲线对试样的耐腐蚀性能进行检测分析.利用电子背散射衍射技术和透射电镜对3种试样的显微组织进行表征,研究耐腐蚀性能的变化机理.结果 经搅拌摩擦加工后,样品的阻抗值明显提高,动电位极化曲线测试结果显示,母材、FSP试样和复合材料试样的自腐蚀电位分别为–1.517、–1.338、–1.339 V,而腐蚀电流密度分别为0.48、0.11、0.12 mA/cm2.FSP加工试样的晶粒由平均晶粒尺寸为8.7μm左右的等轴晶粒构成,并且大部分析出相因高温作用发生溶解,而纳米SiC粒子的加入,使晶粒尺寸进一步降低至4.1μm左右.结论 所制备Al6061/SiC复合材料的耐腐蚀性能相较于母材明显改善,但弱于FSP试样.SiC和基体之间电位差的存在构成腐蚀微电池,降低材料的耐腐蚀性能,而晶界数量的增加造成点阵空位等缺陷增加,导致电荷转移的阻力增加,耐腐蚀性能得到改善.     

低合金超级贝氏体钢组织形态的研究

针对贝氏体研究中的超级贝氏体组织,设计了试验用钢70MnSi2CrMo,经低温等温处理,获得贝氏体铁素体+残余奥氏体的组织,利用X射线衍射XRD、扫描电子显微镜SEM、透射电子显微镜TEM等仪器对其进行相组成和形态的检测分析.结果表明:在马氏体转变开始温度Ms点稍上的中低温区等温处理,贝氏体铁素体沿γ相晶界转变,无碳化物析出;α相转变排碳导致成分起伏,α/γ交界处过冷奥氏体稳定性增加,难以转变成马氏体;贝氏体铁素体的转变特征、过饱和的碳浓度、高密度位错、以及纳米尺寸相界面和亚结构等,影响着超级贝氏体钢的力学性能.     

75Si2Mn1.5CrB铸钢等温淬火组织及力学性能

对新型的高碳低合金75Si2Mn1.5CrB钢进行了在200℃等温淬火工艺组织和力学性能的研究。利用激光显微镜、透射电子显微镜(TEM)和X射线衍射仪(XRD)对等温淬火处理的试验用钢进行了观察和分析。结果表明,75Si2Mn1.5CrB钢经920℃奥氏体化快冷至200℃等温处理后,组织为带有奥氏体薄膜的贝氏体铁素体、马氏体和残留奥氏体。75Si2Mn1.5CrB钢在200℃等温22 h时,其综合力学性能良好。     

Improved mechanical properties of reaction-bonded SiC through in-situ formation of Ti3SiC2

Reaction-bonded SiC is a ceramic with excellent thermal properties, good corrosion resistance and the characteristic of near-net-shape manufacturing. However, the poor fracture toughness of free Si limits the applications of reaction-bonded SiC. In this study, TiC was added to reaction-bonded SiC and reacted with free Si to form Ti₃SiC₂. The effects of TiC and carbon black on the mechanical properties of reaction-bonded SiC were investigated. The results demonstrated that the in-situ formation of Ti₃SiC₂ and decrease in the content and size of free Si improved the mechanical properties of reaction-bonded SiC ceramics. The mechanical properties of TiC-added reaction-bonded SiC with 17.5 wt% carbon black were superior to those of TiC-added reaction-bonded SiC with 15 wt% carbon black. Moreover, increasing the TiC content of reaction-bonded SiC with 17.5 wt% carbon black from 0 to 7.5 wt% caused an increase in its bending strength from 183.92 to 424.43 MPa and an increase in fracture toughness from 3.7 to 5.24 MPa m^1/2.